Abstract
A survey of 102 structures flagged with 'absolute configuration' in the Cambridge Crystallographic Data Centre files for 1982 reveals many unsatisfactory features in the original publications. These are associated with data collection (lack of Friedel opposites and of absorption corrections), misinterpretation of the term 'absolute configuration' (claimed for achiral molecules and space groups), methods used to determine absolute configuration (over-optimistic interpretation of discriminatory tests) and presentation of results (little experimental detail, no prominent statement that an absolute configuration was assigned, no clear description of the methods used). Some confusion arises because of unintentional flagging of absolute configurations determined by solely chemical means.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Acta Crystallographica Section A Foundations of Crystallography
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.