The density profiles of N2([formula omitted]) and N2([formula omitted]) in the Pink Afterglow of the DC nitrogen flowing discharge

Abstract

We have studied by optical emission spectroscopy (OES) the afterglow of a nitrogen DC flowing discharge in such experimental conditions that the Pink Afterglow (PA) was present in the post-discharge. The spectra were recorded in the range of 360–435nm. The emissions of the second positive system of the nitrogen molecules concerning the transitions N2(C3Πu, v)→N2(B3Πg, v′) with Δv=−2 and the emissions of the first negative system concerning the transitions N2+(B2Σu+,v)→N2+(X2Σg+,v′) with Δv=−1 were utilized to furnish the relative density of the N2(C3Πu, 0⩽v⩽4) and the N2+(B2Σu+,0⩽v⩽6) populations from that we have estimated the total density of the N2(C3Πu) and N2+(B2Σu+) electronic states. A kinetic numerical model was constructed for modeling the nitrogen post-discharge. The density profiles of the electronic states N2(C3Πu) and N2+(B2Σu+) obtained experimentally were fitted by the calculated density profiles furnished by the model. In this sense, we have calibrated the numerical model that will be employed in the calculation of the coefficients applied in the estimation of the N2(A3Σu+) and N2(a′Σu-) density profiles. We have developed a method of combined application of the OES and numerical modeling which permits the estimation of the N2(A3Σu+) and N2(a′Σu-) density profiles from the measured density of the N2(C3Πu) state corrected by the calculated coefficients. The estimated density profiles are compared to the calculated ones generated by the kinetic model. The N2(A3Σu+) densities along the afterglow obtained by our method are compared to those ones measured by intracavity laser absorption spectroscopy (ICLAS) (Sadeghi et al., 2001 [14]). The N2(a′Σu-) density profile in the PA, based on experimental data, is estimated for the first time here. The N2(A3Σu+) density found in the maximum of the Pink Afterglow is 2.0×1011cm−3 and the density of the N2(a′Σu-) state is 1.3×1011cm−3. The discharge operated at 30mA electric current, 500Pa gas pressure and 500sccm flow rate.