Abstract
The energy of activation (E a) of the dehalogenation reaction induced by Bu 3Sn was measured for some aryl, alkyl and benzyl halides. BDE values of the CX bond undergoing homolysis were obtained from thermochemical cycles, and correlated with the E a values. No major effect due to the polarity of the CX bond was found. Durene derivatives showed a buttressing effect. A comparison of the homolytic BDE of the CX bond of organic halides with the BDE of the CX bond in the radical anion of the same precursors is reported.
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