Abstract
A definition of the thermodynamic entropy based on the time-dependent probability distribution of the macroscopic variables is developed. When a constraint in a composite system is released, the probability distribution for the new equilibrium values goes to a narrow peak. Defining the entropy by the logarithm of the probability distribution automatically makes it a maximum at the equilibrium values, so it satisfies the Second Law. It is also satisfies the postulates of thermodynamics. Objections to this definition by Dieks and Peters are discussed and resolved.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Physica A: Statistical Mechanics and its Applications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.