Abstract

A formula for the calculation of the three g factors of 3d9 ions in an orthorhombic field D2h has been derived. Using it to investigate the EPR g factors of the Cu2+ ions in single crystals of Cu0.5Zr2(PO4)3, the variation of the g factors on changing the angle α between the x- and y-axis has been explained. According to that, it can be confirmed that the angle α of the D2h distortion is about 62.6°. PACS: 71.70C; 76.30F

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