Abstract
The [V6O13{(OCH2)3CCH2OCH2C[triple bond, length as m-dash]CH}2]2- with two terminal alkyne functionalities exhibits excellent reactivity towards (bio-)organic azides. The designed synthetic protocol for the generation of triazol-modified Lindqvist hexavanadates grants access to bio-"clicked" polyoxometalates with spectroscopically detectable 51V nuclei.
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