Abstract

AbstractThe crystallization in GeO2‐NaCl‐H2O, CdO‐NaOH(NaCl)–H2O. CdO–GeO2–H2O, CdO–GeO2–NaOH (NaCl)–H2O systems investigated under hydrothermal conditions depending on the initial ratio of CdO and GeO2 oxides in starting material and solvent concentration. Single crystals of six Cd‐germanates and five accessory compounds are obtained. The influence of the mineralizer on Cd‐germanates crystallization and the chemism of the interaction of the charge components and the solvent are discussed.

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