Abstract
Abstract The title compound, Cu[C6H18N4](PF6)2, is orthorhombic, with space group B2mb and Z = 4. The cell dimensions are: a = 7.362(1) Å, b = 14.708(5) Å and c = 15.551(6) Å. A total of 1623 independent reflections were measured with a SYNTEX P21 automatic diffractometer using MoKα radiation. The structure was refined by full-matrix least-squares to a conventional R factor 0.0693 for 1560 unique reflections. The co-ordination around the central copper atom is octahedral with the copper atom 0.096(18) Å below the equatorial plane of the four nitrogen atoms of the ligand molecule. The Cu – N equatorial plane bond lengths have a mean value of 1.9815 Å. The remaining positions of the co-ordination octahedron are occupied by two fluorine atoms of the fluorophosphate groups. The Cu – F bonds have lengths of 2.5901 Å and 2.6014 Å.
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