Abstract
The crystal of the 1:1 complex of cyclomaltoheptaose (β-cyclodextrin, βCD) with 4- tert-butylbenzoic acid is triclinic P1 with a = 18.244(3), b = 15.476(3), c = 15.417(2) A ̊ ; α = 102.94(1), β = 113.08(1), γ = 99.69(2)°; V = 3740(1) A ̊ 3 ; and Z = 2. The final R was determined to be 0.0932 for 8111 observed reflections (Mo Kα radiation). Two independent molecules of βCD form a dimer, via hydrogen bonds involving the O-3 n atoms, that encloses two molecules of 4- tert-butylbenzoic acid. The guest molecules penetrate the βCD cavities to different depths. There are 26.8 water molecules, distributed over 30 sites, which form a dense water network surrounding the dimers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
