Abstract
The structure of [Pt(Et 2dtc)(P 2P′)]BPh 4 (Et 2dtcS 2CNEt 2 and P 2P′PhP(CH 2CH 2PPh 2) 2) has been determined from three-dimensional X-ray data. Monoclinic crystals of the complex belong to the space group P2 1/c with cell dimensions a=18.375(2), b=15.724(2), c=20.426(3) Å, β=108.85(1)°, V=5585(3) Å 3, Z=4. Residuals are R=0.034 and R w=0.044 for 4092 observed data. The phosphine ligand is chelated via all three phosphorus atoms while the dithiocarbamate ligand is monodentate, through one sulfur atom, to give a distorted square planar arrangement about the platinum atom. The short non-bonding distance (2.754(3) Å) between the platinum and other sulfur atom indicates there may be some interaction between these two atoms in the solid state.
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