Abstract
Crystals of di-μ-chloro-bis([trichloro(ethyl acetate)]dizirconium(IV) are monoclinic, space group P2 1/ a, Z = 2, with cell dimensions a 13.756(10), b 9.331(6), c 9.270(9) Å, β 110.85(7)°. The structure was refined by full-matrix least-squares to R = 0.040 for 1812 non-zero reflections. In the centrosymmetric [Zr 2(μ-Cl) 2Cl 6(CH 3COOEt) 2] dimer molecules, each of zirconium atoms is bonded to two bridging chlorine atoms, three terminal chlorine atoms and to one carbonyl oxygen atom of the ethyl acetate molecule in a distorted octahedral environment. The structure is isomorphous with that of di-μ-chlorobis[trichloro(ethyl acetate)di-titanium(IV).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
