Abstract
Abstract X-Ray structure analysis of the title compound has revealed that the asymmetric secondary nitrogen center in the complex cation has the S absolute configuration. The crystals are orthorhombic, with the space group P212121and with Z=4 in a unit cell with dimensions of: a=18.783(6), b=14.138(4), and c=8.473(2)Å. The crystal structure has been determined from three-dimensional diffractometer data and refined by the least-squares method to R of 0.030 for 1971 independent reflections with I>3σ(I). The Pt atom has a square-planar coordination by four N atoms, and the methyl group bonded to the secondary nitrogen is equatorial with respect to the chelate ring. Each complex cation is surrounded octahedrally by six di-μ-(+)-tartrato(4-)-bis(antimonate(III)) anions.
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