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Abstract
Triphenylsilylthiirane, crystallized from anhydrous pentane, has the cell dimensions: a 16.452(6), b 11.440(2), c 19.192(7) Å; β 105.39(3)°; V 3483(2) (Å 3; Z 8; space group C2/ c. The structure was solved by direct methods and refined anisotropically down to R 0.094. The triphenylsilyl group has a propeller conformation. The thiirane ring shows a significant thermal motion.
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