Abstract
The crystal and molecular structures of the title compound have been determined by single crystal X-ray diffraction methods. In the spiro molecule, the metal atom has a geometry very close to tetrahedral, with OTiO angles of 107.9–111.0(2)° and very short TiO bonds of length 1.777–1.791(5)Å. The two TiO 5Si 4 rings have different, ill-defined conformations; the SiO bond lengths and SiOSi angles are similar to those in (SiO) n rings.
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