Abstract
The crystal and molecular structure of μ-oxobis[chlorotriphenylantimony(V)]benzene solvate ( 1 2 ) has been determined by single-crystal X-ray diffraction techniques. The dinuclear complex, (Ph 3SbCl) 2O, features a bent SbOSb bridge (139.0(3)°), short SbO(bridge) bond distances of 1.980(6) and 1.986(6) Å, and relatively long SbCl bond lengths of 2.553(2) and 2.582(3) Å. Crystals are triclinic, space group P 1 , with unit cell parameters a 12.974(5), b 13.716(7), c12.865(5) Å, α 110.04(4), β 97.52(3), λ 77.70(4)° with Z = 2. Refinement on 3314 reflections (with I ≥ 2.5σ( I)] converged to final R = 0.045 and R w = 0.047.
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