Abstract
Abstract The crystal and molecular structure of the title complex was determined by the single-crystal X-ray diffraction method. The crystallographic data are: monoclinic, space group P21⁄c, a=19.164(6), b=19.020(9), c=18.649(7) Å, β=95.06(3)°, and Z=8 (16 metal atoms are in a unit cell). There are two crystallographically independent dimeric [SbBr(C6H5)3]2O molecules, which are almost in the same form. Each antimony atom is bonded with three phenyl carbon atoms equatorially and one bromine as well as one bridging oxygen atoms axially, being in a trigonal-bipyramidal geometry. The Sb–O–Sb′ angles are 170.2(7) and 176.6(8)°, while the Sb–O lengths are in the range of 1.931(13)—1.958(13) Å, which are shorter than the sum of their covalent radii of the atoms: 2.15 Å.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
