Abstract

The corrosion of vanadium, niobium and tantalum in flowing, liquid sodium has been examined. The ternary oxides, Na 4VO 4 and NaVO 2 have been observed on the surface of vanadium, through a matrix of sodium, by X-ray diffraction, together with an oxygen solid solution in the vanadium. For niobium and tantalum, only a single, ternary oxide corrosion product, Na 3MO 4(M = Nb, Ta), was observed, together with an oxygen solid solution. It has been concluded that Group 5A metals will form ternary oxide corrosion products when exposed to liquid sodium at 600 °C containing more than five parts per million of oxygen.

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