Abstract

A “molecular dynamics” computer simulation of liquid CH 2 Cl 2 and CHCl 3 has revealed a time dependence of the simple kinetic energy correlation function 〈v 2 (O)J 2 (t)〉/(〈v 2 (O)〉〈J 2 (O)〉) where v is the c. of m. linear velocity and J the molecular angular momentum. This is constant at unity for all t in conventional analytical theory, which is therefore in need of development. The variates v and J are not Gaussian during the approach to equilibrium.

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