Abstract

The monitoring and analysis of concentrations of toxic metals (lead and cadmium) in soils and crops indicate that farmland in Serbia is generally not polluted, and the quality of soils is naturally good. Such soils are therefore suitable for organic farming. All noted instances of contamination by toxic metals are of a local nature only, and the result of fertilizers and pesticides, municipal waste, exhaust gases, nearby production facilities, smelting plants, mines, tailings ponds, etc. Locations of this type need to be monitored regularly, and the status of the soil and crops assessed. The results presented in this paper place special emphasis on lead and cadmium. In this regard, the sampling of 67 plant foodstuffs that are being grown in Baroševac village, located in the immediate vicinity of the Kolubara coal mine, was carried out. Fruit samples represented 14.9% and vegetable samples 85.1% of the total sample. The heavy metal content (lead/cadmium) in seven samples was above the limits prescribed by the Regulations. Overall exposure of the adult population of Baroševac, calculated on the basis of all samples (67 in total), was 0.89 µg lead per kg of body weight per week, representing only 3.5% provisional tolerable weekly intake (PTWI), and 0.46 cadmium per kg of body weight, which amounts to 6.7% PTWI. Both values point to the fact that the risk is low, even in the case of populations with high exposure to these toxic metals. This suggests that sustainable development may be possible in the near future.

Highlights

  • Speaking, the problem of the quality of agricultural produce is becoming a problem on a global level

  • The increase of the presence of heavy metals in soils and food is matched by the increase of studies of the consequences of their impact on human health [30,31,32,33,34,35,36,37,38,39]

  • According to national standards concerning residues of plant protection agents in produce and animal feed and the prescribed threshold levels [40], lead concentrations in excess of threshold values were detected in seven produce samples

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Summary

Introduction

The problem of the quality of agricultural produce is becoming a problem on a global level. Mines, large landfills, etc., have a direct impact on people living in their surroundings, and an indirect impact, through food produced in the wider environment of these large sources of pollution, when consumed by people from the same locality or when it gets to the market. The present paper does not aim to provide the final answer to this question Instead, it presents the results of research on toxic metals in produce sampled from gardens in the immediate vicinity of open-pit coal mines, to draw attention to the need to examine the effect of mining on the environment. Valid data and unbiased assessments will lead to an answer that is important to all those associated in any way with the mining industry

Toxic Metals in Soils and Food
Produce Sampling Method
Exposure Assessment
Results
Lead and Cadmium Concentrations in Produce
Deterministic and Semi-Probabilistic Risk Assessment
Discussion and Conclusions
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