Abstract
AbstractAnhydro monosaccharide is a specific and distinctive category of carbohydrates, which is found in many naturally derived and artificial bioactive substrates. In the field of organic chemistry, some anhydro sugars can be used as common synthons to construct different carbohydrate structures. The development of efficient methodologies for the construction of various anhydro sugar fragments is very important in carbohydrate chemistry, which has attracted considerable attention in the past few years. This review mainly covers the development of new synthetic methods since 2000 and gives an overview of the development in the formation of anhydro monosaccharide structures. It systematically summarizes all methods to establish an intramolecular ether bridge in furanose and pyranose structures, which are the most commonly used monosaccharide fragments in carbohydrate chemistry.
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