Abstract
Variable-temperature 13C n.m.r. shows the title compound to be the trans-isomer which adopts a symmetric conformation with the C-methyl groups diequatorial and the N-methyl groups symmetrically diaxial diequatorial (aeae). The N-inversion barrier (ΔGc‡ 7.7 kcal mol–1) provides strong evidence for the three conformational sets previously postulated for 1,2,4,5-tetra-azacyclohexanes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have