Abstract
In a previous paper, the effect of the Ag 2O on the electrical conductivity of vanadium tellurite glasses of the form XAg 2O·(1− X)V 2O 5·2TeO 2 has been studied by using the impedance spectroscopy in a wide range of temperature and composition. The obtained results confirm the existence of a transition from a typically electronic (polaronic) conductive regime when the molar fraction ( X) of Ag 2O is equal to 0 to an ionic conductive regime when X tends to 1. This transition is characterised by a deep minimum in the electrical conductivity of about three orders of magnitude. In the present paper, a complementary study of the system of the form XAg 2O·(1− X)[0.5V 2O 5–0.5MoO 3]2TeO 2 is reported. The correlated behaviour between conductivity and the mean distance between silver ions and between vanadium ions for these two systems reinforces the idea of two independent migrating paths for both electrons and ions, respectively.
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