Abstract
The condensation of benzaldehyde with methyl and ethyl α-aryl-β-benzoyl propionates in the presence of sodium methylate, followed by acidification, gave unsaturated ketonic acids. This result was unexpected in view of the previously described similar work in which lactols were formed; the only difference in the molecules is the absence of a substituent group in the benzoyl radical of the ester.The structure of the acids was carefully determined. On being heated they lost carbon dioxide, forming α, β-unsaturated ketones. One of the latter added hydrogen chloride to give two stereoisomeric saturated chloroketones, which were also synthesized by an independent method.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
