Abstract
Abstract Several phosphoramidates were reacted with dried hydrogen chloride, acetic acid, and oxalic acid. The phosphoramidates reacted with the acids to produce ortho- and polyphosphates, but did not react with them to make polyphosphates containing imino groups, with the elimination of ammonia. The decomposition of the phosphoramidates to orthophosphate by the action of water was considered to be the first step in the production of polyphosphates: (Remark: Graphics omitted.), The formation of polyphosphates can be explained, for example, by this equation: (Remark: Graphics omitted.), where HA stands for acid.
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