The complex atmospheric corrosion of α/δ bronze bells in a marine environment

Abstract

• Long term corrosion of a high-tin bronze bell in a steeple under marine atmosphere. • A corroded high-tin α/δ alloy Cu-Sn-Pb: comparaison with ancient buried artefacts. • Complex alteration due to environment, shocks and vibrations of bells. • Particular pitting corrosion of α/δ alloy. • Hypothesis of a micro-infiltrating alteration scenario of the α/δ bronze bell. α/δ bronze bells are heritage materials subject to corrosion. The alteration of a high-tin bronze bell casted in the 1930s and exposed to a marine environment in a steeple was studied. The ternary bronze (Cu-Sn-Pb) alloy displays inclusions and a porosity due to micro-shrinkages and poor gas evacuation. This altered bronze is characterized to (1) assess the influence of the manufacturing techniques and (2) hypothesize a micro-infiltration scenario of its alteration. After exposure to the atmosphere, a transformed superficial medium overlaying layers of atacamite-paratacamite-cassiterite appears. Under them, the corrosion of the α dendritic structure and α/δ eutectoid characteristic of bronze bell is evidenced. The α pitting has a pronounced multilayered structure of cassiterite and cuprite-copper chloride, whereas the δ corrosion is composed of cassiterite and traces of cuprite. To understand better the lead impact on corrosion process, samples of the alloy were exposed in the laboratory to a synthetic marine solution. The long-term corrosion behavior of the studied bell shows some similarities to those of other high tin bronze artefacts. The hypothesis of a corrosion scenario emphasizes the importance of the bells manufacturing techniques, α/δ structure of the ternary Cu-Sn-Pb alloy, and infiltrating networks of environmental fluids.