Abstract
Abstract Polypyridineruthenium(II) complex with linked viologen units was synthesized as the model of man-made photoreaction center. Luminescence quenching of the ruthenium complex by a surfactant-type viologen in micellar or bilayer membrane systems was resolved into inter- and intramolecular processes and it became apparent that the photoinduced charge separation in intramolecular process was more efficient than that in intermolecular process.
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