The comparative effect of HMX content on the detonation performance characterization of PBX 9012 and PBX 9501 high explosives

Abstract

A series of detonation performance experiments are described for the plastic-bonded high explosive (HE) PBX 9012, nominally composed of 90% octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazine (HMX) and 10% polymeric binder vinylidene-hexafluoropropylene copolymer (Viton VTR-5883), by weight. The experiments provide information on the PBX 9012’s detonation propagation properties and metal pushing characteristics. Although this HE formulation has been in use for 50 years as a booster (compositionally similar to LX-07), our new data represent the first full detonation performance characterization for the HE (along with recently reported shock initiation experiments). Here, we compare the new PBX 9012 data with the well-studied PBX 9501 (95% HMX and 5% polymeric binder), establishing how the 5% difference in HMX content between the explosives is manifested in the performance measurements. A scaling argument based on the known energetic material content in a large selection of high HMX content formulations is also given to help explain the observed results. Finally, the accumulated PBX 9012 data is used to generate performance models using both programmed and reactive burn techniques, providing an additional avenue to compare PBX 9012 to the more energetic PBX 9501.