The Color of High Energy Density Gold

Abstract

Summary form only given. The study of non-equilibrium phase transitions is a rapidly developing field. Non-thermal melting has been observed in femtosecond laser heated semiconductors such as silicon. This is thought to result from the excitation of valence electrons to the conduction band, giving rise to anti-bonding states. In metals, the process of melting under ultrafast laser excitation is not clearly understood. In our experiment, we measure the broadband (400-800 nm) optical reflectivity and transmissivity of freestanding, 30 nm-thick gold foils heated with 150 fs, 400 nm laser light. Prior to laser excitation the sample shows strong reflectivity for wavelengths above 500 nm. This is due to interband (d to s/p) transitions, thus giving gold its characteristic color. The reflectivity and transmissivity spectra of the heated sample (hence the color of gold) change substantially with laser excitation energy densities. Such spectral signatures offer a new means of probing electronic and structure behaviors associated with non-equilibrium phase transitions