Abstract
Unexpectedly small: The CoII crystal-field parameter in CoFe Prussian blue analogues is smaller than for any other octahedral CoII(high-spin) molecular entity and it seems to be determined by the geometry of the Co coordination polyhedron, which is imposed by weak and strong cooperative interactions within the 3D structure rather than by the chemical nature of the ligands (see picture).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
