The classical theory of dispersion

Abstract

Classical dispersion theory Many aspects of the interaction between radiation and matter can be described quite accurately by a classical theory in which the medium is represented by model atoms consisting of positive and negative parts bound by an attraction which depends linearly on their separation. Although quantum theory is necessary to calculate from first principles the magnitude of the parameters involved, in this chapter we shall show that many optical effects can be interpreted physically in terms of this model by the use of classical mechanics. In §13.5 we shall relax the restriction of linearity. Some of the quantum mechanical foundations will be discussed briefly in Chapter 14, but most are outside the scope of this book (see Yariv, 1989; Loudon, 1983). The term dispersion means the dependence of dielectric response (dielectric constant and refractive index) on frequency of the wave field. This will be the topic of the present section. Afterwards we shall see some of the applications of dielectric response to spatial effects. The classical atom Our classical picture of an atom consists of a massive positive nucleus surrounded by a light spherically-symmetrical cloud of electrons with an equal negative charge. We imagine the two as bound together by springs as in Fig. 13.1, so that in equilibrium the centres of mass and charge of the core and electron charge coincide. As a result the static atom has zero dipole moment.