Abstract

The semi-rigid inversion hamiltonian is used to fit the rotation-inversion energy separations of formaldehyde in the A1 A2 excited electronic state. In the model the HCH angle is a function of the inversion coordinate which is defined as an angle between the CO bond and the HCH plane. It is noticed that the CO and CH bond lenghts calculated, here are different from those obtained whithin the rigid approach.

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