Abstract
Abstract The Chemla effect was discovered in 1958 on the try to enrich isotopes in a molten mixture system (Li, K)Br. Since then internal or external mobilities have been measured in various binary cation systems with a common anion, and the Chemla effect has been found to be rather common in binary monovalent cation systems. Interpretation of the Chemla effect has become a crucial key to a better understanding of the mechanism of electric conductance in molten salts. The Chemla effect can also be exploited for isotope separation of monovalent metal ions, and should be taken into account in the choice of the composition of electrolytes in molten carbonate fuel cells.
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