Abstract
A review is given of recent syntheses of polyfluoroaromatic derivatives of group VA and VIA elements and their reactivity. The reactivity of N,N-dichloropolyfluoroanilines, polyfluorinated azoxybenzenes and other compounds is analysed. A new approach to oxidation of group VA elements in strong oxygen-containing acids is discussed. UV photoelectron (He I), X-ray fluorescent and Raman spectroscopic data are reported. Influence of the electronic structure of fluorine on polyfluorinated aromatic system is discussed on the basis of FKα -emission spectra. A relationship has been obtained between the electronic structure and the reactivity of polyfluoroaromatic derivatives of group VA and VIA elements.
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