Abstract

In order to obtain a better understanding of the decomposition mechanisms of antiwear and antioxidant engine oil additives such as zinc dialkyldithiophosphate (ZDDP) and molybdenum dithiocarbamate (MoDTC), tribochemical and thermally deposited films were prepared from oil solutions containing varying concentrations of these two additives. The chemistry of these films was studied by using X-ray absorption (XANES) spectroscopy and X-ray photoelectron (XPS). The antiwear properties were examined on a Plint rubbing machine by measuring the amount of wear as a function of time and the concentrations of the additives. The XANES and XPS spectra indicate that the dominant species from MoDTC in the antiwear films resembles that of a MoS2-like film, and in the thermal films, the dominant species are those of a sulphate and MoO3. The spectra also indicate that the phosphorus from ZDDP forms polyphosphate chains of varying lengths. The combined use of organo-Mo compounds and Zn alkyl dithiophosphates showed a synergistic effect by reducing both friction and wear. Presented as a Society of Tribologists and Lubrication Engineers paper at the World Tribology Congress in London, United Kingdom, September 8–12, 1997

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.