The chemistry and the stereochemistry of poly( N-alkyliminoalanes) : XV. The crystal and molecular structure of the compounds [((THF)Mg)(HA1N-t-Bu) 3] and [((THF) 3Ca)(HA1N-t-Bu) 3] · THF

Abstract

The compounds [((THF)Mg)(HA1N-t-Bu) 3] (I) and [((THF) 3Ca)(HA1N-t-Bu) 3] · THF (II) have been structurally characterized from single-crystal diffraction data. The molecular structures are based on an (A1N) 4 “cubane” type framework in which an aluminum is replaced by an alkaline earth metal. According to the size and the coordination of the “foreign” atom (four for Mg, six for Ca) the cubic geometry of the cage is increasingly distorted. Coordination is completed by one molecule of THF to the Mg atom and three molecules to the Ca atom; in II a molecule of THF crystallizes with a cage molecule. Mean MgN and CaN bond distances are 2.090(4) and 2.490(2) Å. Crystal data: I, orthorombic, space group Pbca, a 17.107(2), b 17.305(4) and c 20.220(5) Å, Z = 8, calculated density 1.031 g/cm 3; II, orthorombic, space group Pbca, a 20.48(1), b 20.38(1), c 20.51(1), Z = 8, calculated density 1.081 g/cm 3.