The chemistry and origin of zincian spinel associated with the Aggeneys Cu-Pb-Zn-Ag deposits, Namaqualand, South Africa

Abstract

Zincian spinel or gahnite [(Zn,Fe,Mg)Al2O4] occurs in metamorphosed sulphide-rich rocks, garnet quartzites, quartz-magnetite rocks, aluminous metasediments, barite-magnetite rocks, quartz veins, and pegmatites associated with the Aggeneys base metal deposits, Namaqualand, South Africa. Zincian spinel in, sulphide-bearing rocks, is considered to have formed predominantly by desulphurization reactions involving a member of the system Fe-S-O and sphalerite with sillimanite or garnet. Gahnite in sulphide-free garnet quartzites, quartz-magnetite rocks and barite-magnetite rocks probably formed from Zn and Al that were hydrothermally derived whereas gahnite in aluminous metasediments was derived from the metamorphism of metalliferous shales, in which Zn may originally have been linked to organic material. Gahnite is Zn-rich in sulphide-bearing rock, but is Fe-rich in sulphide-free garnet quartzites and quartz-magnetite rocks. Although Zn-rich spinels represent guides to ore in the Aggeneys area and elsewhere in the Namaqualand Metamorphic Complex, Fe-rich spinels should not be discounted because Zn-rich and Fe-rich spinels occur within metres of sulphides at Aggeneys.