Abstract
Flash pyrolysis tars from one brown and two bituminous Australian coals were separated into oils, asphaltenes and pre-asphaltenes. The oils were further separated by chromatography while the asphaltenes were separated into basic and acid/neutral fractions. The pre-asphaltenes were silyalated prior to 13C- and 1H-n.m.r. studies. The brown coal tar was less aromatic and contained more long alkyl chains than the tars from the bituminous coals. Aliphatic constituents of the oils, which were relatively abundant, consisted mainly of n-alkanes and straight chain 1-alkenes with an average chain length of ca. C 13. The pre-asphaltenes were no more aromatic than the asphaltenes from the same tar but had higher molecular weights.
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