Abstract
With the effective control of point source pollution, rainfall runoff pollution has become the main source of water pollution in Xi'an. Understanding the characteristics and driving factors of rainfall runoff pollution would provide theoretical foundation for urban rainfall runoff pollution control. In this study, a total of 32 rainwater samples, 604 roof runoff samples and 608 road runoff samples obtained from literature and a total of 35 rainwater samples, 127 roof runoff samples and 70 road runoff samples collected by our group were mixed to analyze the rainfall runoff pollution from 2008 to 2019. The Mann-Kendall and Logarithmic Mean Divisia Index (LMDI) method were used to determine the trend of pollution and the driving factors of water quality changes. The results showed that the major pollutant from rainwater was nitrogen, while the main pollutants from roof and road runoff were COD and SS. The rainwater quality during the study period was “clean to slightly polluted”. The roof runoff quality of most years (67%) was “clean to slightly polluted”. The road runoff quality was poor: 22% was “moderately polluted”, and 45% was “heavily polluted”. The concentration of pollutants except COD in rainwater showed a decreasing trend, while the trend of pollutants in roof and road runoff was not completely consistent with that in rainwater. NH3-N showed strong positive correlation with TN in roof runoff, which indicated common sources of these pollutants. There was a significant correlation between SS and COD in road runoff, and between SS and TP in roof runoff, suggesting SS was an important carrier of COD and TP. Technology innovation was the dominant factor affecting water quality, followed by industrial structure. Economic development and population scale contribute negatively to water quality improvement, and there was a sharp increase in the population scale effect in 2017.
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