Abstract

The energy conditions for the formation of the compounds under the conditions of heterogeneous equilibrium were studied using the Filippov eutonic method, permitting the ΔG° values for the reactions leading to the formation of the above double selenates to be obtained directly. The values obtained, which varied in the range -17.8 to -24.4 kJ mol-1, were correlated with the solubilities of the compounds formed and the selenates M2SeO4. The interaction M2SeO4-MgSeO4 in the liquid phase was also studied.

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