Abstract
AbstractThe iron(II)‐ iron(III) electron‐exchange rate has been measured at 0° in aqueous perchloric acid‐sodium perchlorate and perchloric acid‐lithium perchlorate mixtures of varying acid concentration, at three values of the ionic strength.The medium effects upon the rate of this reaction are interpreted as a result of a) the displacement of hydrolysis equilibria with the hydrogen ion concentration, and participation of the hydrolyzed ions in the exchange reaction, and b) the variation of the activity coefficients of the reacting species with the hydrogen ion concentration.
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