The Cathode-Electrolyte Interface Constructed with Antioxidant Ascorbic Acid Guides LNMO to Achieve Stable Cycling Under High Voltage Conditions.

Abstract

LiNi0.5Mn1.5O4 (LNMO) is considered one of the most promising cathode materials for high-energy-density lithium-ion batteries (LIBs). However, free-radical-induced carbonate electrolyte decomposition is a key factor hindering the improvement of battery stability. Inspired by the antioxidative properties of ascorbic acid (AA) in scavenging free radicals, the addition of AA during the electrode fabrication process can effectively terminate free radical chain reactions within the cycling of LNMO. This action prevents severe electrolyte decomposition, thus stabilizing the cathode-electrolyte interface (CEI) and ultimately enhancing battery stability. The results demonstrate that LNMO||Li half-cell with the addition of AA show significantly improved cycling performance after 1000 cycles at 1 C, with a high capacity retention rate of 87.4%, surpassing the 43.6% retention rate achieved by batteries using PVDF alone as a binder. This work introduces an efficient and straightforward strategy for designing functional additives to stabilize phase interfaces, offering an economically efficient choice to enhance the electrochemical performance of the LNMO.