Abstract
The crystal structures of neutral cis- and trans-[Pt(dimethyl sulfoxide)(thiazole)Cl 2] have been determined by X-ray diffraction. The longer C4–C5 bond distance of the N-coordinated thiazole in both the square planar complexes, as compared to the free ligand, is interpreted in terms of a negative charge density transfer toward the antibonding orbital system of the thiazolic ring.
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