Abstract
The reaction of thioglycerol with quinones selected to model the chromophores present in high-yield pulp has been investigated. The reaction is rapid and complex, involving initial Michael addition, aromatization of the adducts to hydroquinones, and reoxidation of those hydroquinones to new chromophores. The Michael addition is responsible for the bleaching effect of thioglycerol upon pulp, and the reoxidation is responsible for the eventual development of more intense color by treated pulp. Semi-empirical and ab initio molecular orbital calculations have been used as an aid to rationalizing the experimental results.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
