Abstract
The charge transfer salt, (ET)5PVMo11O40·2H2O [ET=bis(ethylene)-dithiotetrathiafulvalene], was prepared by reducing the diamagnetic molybdovanadophosphoric heteropoly acid (H4PMo11VO40·nH2O, HMVP) with the organic donor ET. The u.v.-vis spectrum of the complex shows an electronic transfer band at 900nm. The i.r. and Raman spectra suggest that the ET donor molecules are all completely ionized. Magnetic measurements indicate the presence of antiferromagnetic interactions in the ET organic sublattice. The e.s.r. spectrum exhibits a VIV signal with g=1.9718 and a=57.5cm−1. Over the measured temperature range (75–300K), no significant interaction between the paramagnetic anion and the organic radical cation is observed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
