The binuclear iridium(II) hydride complex [(C(5)Me(5))Ir(mu-H)](2): a novel base for reversible deprotonation of acidic organic compounds and a unique catalyst for C--C bond cleavage of aromatic 1,2-diols and Michael additions.

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTThe Binuclear Iridium(II) Hydride Complex [(C5Me5)Ir(μ-H)]2: A Novel Base for Reversible Deprotonation of Acidic Organic Compounds and a Unique Catalyst for C−C Bond Cleavage of Aromatic 1,2-Diols and Michael AdditionsZhaomin Hou, Take-aki Koizumi, Akira Fujita, Hiroshi Yamazaki, and Yasuo WakatsukiView Author Information Organometallic Chemistry Laboratory RIKEN (The Institute of Physical and Chemical Research) Hirosawa 2-1, Wako, Saitama 351-0198, Japan Department of Applied Chemistry, Chuo University Kasuga 1-13-27, Bunkyo, Tokyo 112-0003, Japan Cite this: J. Am. Chem. Soc. 2001, 123, 24, 5812–5813Publication Date (Web):May 24, 2001Publication History Received23 January 2001Published online24 May 2001Published inissue 1 June 2001https://doi.org/10.1021/ja010186hCopyright © 2001 American Chemical SocietyRIGHTS & PERMISSIONSArticle Views1120Altmetric-Citations37LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit Read OnlinePDF (43 KB) Get e-AlertsSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Anions,Aromatic compounds,Bond cleavage,Deprotonation,Transition metals Get e-Alerts