Abstract
The kinetics of lithium transport across the interface formed by melting lithium onto a lithium nitride sinter has been studied using a linear potential sweep technique. A model which allows the calculation of the product of concentration and diffusion coefficient to be calculated is proposed to account for the observed behaviour. In this model it is suggested that the second mobile species, required for electroneutrality, is hydrogen introduced into the samples during preparation. Infrared absorption measurements carried out on a lithium nitride single crystal during polarisation between lithium electrodes show that both lithium ions and hydrogen ions are mobile.
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