Abstract
The rotationally resolved spectrum of the B2Π–X2Π electronic origin band transition of 13C6H is presented. The spectrum is recorded using cavity ring-down spectroscopy in combination with supersonic plasma jets by discharging a 13C2H2/He/Ar gas mixture. A detailed analysis of more than a hundred fully-resolved transitions allows for an accurate determination of the spectroscopic parameters for both the ground and electronically excited state of 13C6H.
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