Abstract
A simple method for the direct synthesis of 2,2′-binaphthols was developed, utilizing aryl–aryl coupling reaction via electron donor–acceptor complexes of 1-naphthols with SnCl4. Heating of the complex in a sealed tube afforded the corresponding o-o coupling product in excellent yield. This method was utilized for a biomimetic synthesis of the binaphthoquinone, 3,3′-biplumbagin, isolated from Plumbago zeylanica.
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