Abstract

This work was completed in the framework of a cooperation between our institutes at Regensburg and in Lviv, registered under UKR–028–96 at the “Internationales Buro des Bundesministeriums fur Bildung, Wissenschaft, Forschung und Technologie (BMBF) bei der Deutschen Luft- und Raumfahrtgesellschaft (DLR)”, Germany, and Ministry on Science and Technology of Ukraine. The financial support of this contract is gratefully acknowledged.

Highlights

  • It is our pleasure to dedicate this article to I.R

  • To his work belongs a general scheme of plasma-parameter expansions for pair distribution functions of ionic fluids [1], the application of the collective variables method to the correct treatment of long and short-range interionic interactions [2] and the development of the ion-molecular approach for the correct description of solvation phenomena in electrolyte solutions [3,4,5,6]

  • Another important aspect of electrolyte solutions is connected with the ionic association concept introduced by Bjerrum [7] and used in the chemical model apc J.Barthel, H.Krienke, M.F.Holovko, V.I.Kapko, I.A.Protsykevich proach [8,9]

Read more

Summary

Introduction

It is our pleasure to dedicate this article to I.R. Yukhnovskii whose fundamental work in statistical physics yielded a considerable progress in the theory of electrolyte solutions. To his work belongs a general scheme of plasma-parameter expansions for pair distribution functions of ionic fluids [1], the application of the collective variables method to the correct treatment of long and short-range interionic interactions [2] and the development of the ion-molecular approach for the correct description of solvation phenomena in electrolyte solutions [3,4,5,6]. Another important aspect of electrolyte solutions is connected with the ionic association concept introduced by Bjerrum [7] and used in the chemical model apc J.Barthel, H.Krienke, M.F.Holovko, V.I.Kapko, I.A.Protsykevich proach [8,9]. Applications used for the description of the concentration dependence of vapour pressures and conductivities of nonaqueous solutions of associating electrolytes will be discussed

Model and theory
AMSA theory
Modified AMSA including the effect of ion trimers and tetramers
Experimental data
Description of the experimental data with the AMSA
Conclusions
Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.