Abstract

A rough calculation shows that the quadrupole term in the radiation of a forbidden line is usually larger than the dipole produced by an external electric field. This is not true, however, when there is an intermediate state, with which both initial and final states combine, and which lies close to one of them.If the $J$ selection rule is violated, and the Laporte rule is obeyed, the radiation cannot be due to the quadrupole term and must be ascribed to the octopole. Hg 2270 is such a line. An octopole transition will have a Zeeman effect distinctively different from that of a dipole or quadrupole.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.